PPy coated nanoflower like CuCo 2 O 4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes

• Published in: Nanotechnology Vol. 33; no. 15; p. 155606
• Main Authors: Zhao, Zongchen, Zheng, Lili, Li, Haoran, He, Zeyin, Han, Dong, Shi, Jing, Xu, Bin, Wang, Huanlei
• Format: Journal Article
• Language: English
• Published: England 09.04.2022
• Subjects: PPy; nanoporous copper; CuCo2O4; supercapacitor
• ISSN: 0957-4484; 1361-6528
• DOI: 10.1088/1361-6528/ac4660

General CuCo O electrodes suffer a very low reversible capacity and poor cycling stability because of easily fading phenomena and volume change during cycling. To optimize the electrode, a facile method is conducted to fabricate a novel electrode of Cu@CuCo O @polypyrrole nanoflowers. Due to larger specific surface area and more electrochemical reactive areas of CuCo O @polypyrrole nanoflowers, the pseudocapacitance of the grown CuCo O @polypyrrole (912 F g at 2 A g ) is much higher than the pristine CuCo O (618 F g at 2 A g ). Remarkably, the CuCo O @polypyrrole (cathode) and active carbon (anode) are used to assemble an asymmetric supercapacitor, which exhibits a relatively high energy density of 90 Wh kg at a power density of 2519 W kg and 35 Wh kg at a high-power density of 9109 W kg , and excellent cycling stability (about 90.4% capacitance retention over 10 000 cycles). The prominent performance of CuCo O @polypyrrole makes it as a potential electrode for supercapacitor.