Tunable Pseudocapacitance in 3D TiO 2-δ Nanomembranes Enabling Superior Lithium Storage Performance

• Published in: ACS nano Vol. 11; no. 1; pp. 821 - 830
• Main Authors: Huang, Shaozhuan, Zhang, Lin, Lu, Xueyi, Liu, Lifeng, Liu, Lixiang, Sun, Xiaolei, Yin, Yin, Oswald, Steffen, Zou, Zhaoyong, Ding, Fei, Schmidt, Oliver G
• Format: Journal Article
• Language: English
• Published: United States 24.01.2017
• Subjects: Ti3+ self-doping; tunable pseudocapacitance; titanium dioxide; lithium ion battery; 3D nanomembrane
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.6b07274

Nanostructured TiO of different polymorphs, mostly prepared by hydro/solvothermal methods, have been extensively studied for more than a decade as anode materials in lithium ion batteries. Enormous efforts have been devoted to improving the electrical conductivity and lithium ion diffusivity in chemically synthesized TiO nanostructures. In this work we demonstrate that 3D Ti -self-doped TiO (TiO ) nanomembranes, which are prepared by physical vapor deposition combined with strain-released rolled-up technology, have a great potential to address several of the long-standing challenges associated with TiO anodes. The intrinsic electrical conductivity of the TiO layer can be significantly improved by the in situ generated Ti , and the amorphous, thin TiO nanomembrane provides a shortened Li diffusion pathway. The fabricated material shows a favorable electrochemical reaction mechanism for lithium storage. Further, post-treatments are employed to adjust the Ti concentration and crystallinity degree in TiO nanomembranes, providing an opportunity to investigate the important influences of Ti self-doping and amorphous structures on the electrochemical processes. With these experiments, the pseudocapacitance contributions in TiO nanomembranes with different crystallinity degree are quantified and verified by an in-depth kinetics analysis. Additionally, an ultrathin metallic Ti layer can be included, which further improves the lithium storage properties of the TiO , giving rise to the state-of-the-art capacity (200 mAh g at 1 C), excellent rate capability (up to 50 C), and ultralong lifetime (for 5000 cycles at 10 C, with an extraordinary retention of 100%) of TiO anodes.