Light Absorption Properties and Electronic Band Structures of Lead-Vanadium Oxyhalide Apatites Pb 5 (VO 4 ) 3 X (X=F, Cl, Br, I)

The Pb-V oxyhalide apatite compounds Pb (VO ) X (X=F, Cl, Br, I) were successfully synthesized using a facile solution method and studied with respect to their structural/optical characteristics and electronic band structures. UV-visible diffuse reflectance spectroscopy, electrochemical analysis and...

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Published inChemistry, an Asian journal Vol. 15; no. 4; pp. 540 - 545
Main Authors Nakamura, Masashi, Oqmhula, Kenji, Utimula, Keishu, Eguchi, Miharu, Oka, Kengo, Hongo, Kenta, Maezono, Ryo, Maeda, Kazuhiko
Format Journal Article
LanguageEnglish
Published Germany 17.02.2020
Subjects
artificial photosynthesis
visible light
mixed anion compounds
photoelectrochemistry
photocatalysis
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Summary:The Pb-V oxyhalide apatite compounds Pb (VO ) X (X=F, Cl, Br, I) were successfully synthesized using a facile solution method and studied with respect to their structural/optical characteristics and electronic band structures. UV-visible diffuse reflectance spectroscopy, electrochemical analysis and first-principles calculations showed that the synthesized apatites behaved as n-type semiconductors, with absorption bands in the UV-visible region that could be assigned to electron transitions from the valence band to a conduction band formed by hybridized V 3d and Pb 6p orbitals. Among the apatites examined, Pb (VO ) I had the smallest band gap of 2.7 eV, due to an obvious contribution of I 5p orbitals to the valence band maximum. Based on its visible light absorption capability, Pb (VO ) I generated a continuous anodic photocurrent under visible light (λ>420 nm) in a solution of 0.1 m NaI in acetonitrile.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201901692