Stable Cycling of Fe 2 O 3 Nanorice as an Anode through Electrochemical Porousness and the Solid–Electrolyte Interphase Thermolysis Approach

• Published in: ChemPlusChem (Weinheim, Germany) Vol. 79; no. 1; pp. 143 - 150
• Main Authors: Liang, Jianwen, Wei, Denghu, Cheng, Qiushi, Zhu, Yongchun, Li, Xiaona, Fan, Long, Zhang, Jingjing, Qian, Yitai
• Format: Journal Article
• Language: English
• Published: Germany 01.01.2014
• Subjects: surface analysis; iron; electrochemistry; microporous materials; nanostructures
• ISSN: 2192-6506; 2192-6506
• DOI: 10.1002/cplu.201300324

A new thread for improving the cycling stability of Fe 2 O 3 nanorice is proposed through combining the electrochemical porousness (EP) effect and solid–electrolyte interphase (SEI) thermolysis approach. Starting from solid Fe 2 O 3 nanorice, this process could be applied to prepare porous Fe 2 O 3 nanorice with a good coating of a porous SEI thermolysis layer composed of carbon and Li 2 O. The interconnecting pores and full coating of the SEI thermolysis layer provides not only mechanical resistance of the Fe 2 O 3 nanorice against pulverization, but also high electrical and ionic conductivity over the electrode throughout long cell cycles. This method results in the enhancement of cycling ability and capacity, which is demonstrated by comparison with the starting Fe 2 O 3 nanorice. After the EP and SEI thermolysis approach, the Fe 2 O 3 nanorice exhibits an energy capacity retention about of 680 mAh g −1 at a current density of 1000 mA g −1 over 250 cycles, which is more than 82 % of the initial reversible capacity. Moreover, it also has an excellent rate capability and high coulombic efficiency. This strategy provides a simple and convenient route toward stable charge/discharge cycling for not only Fe 2 O 3 , but also for other electrode materials that are subject to large volume changes and low charge voltages. At the same time, it also contributes to a fundamental understanding of improved cycling stability and reversible capacity for electrode materials.