TiO 2 Feather Duster as Effective Polysulfides Restrictor for Enhanced Electrochemical Kinetics in Lithium-Sulfur Batteries

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 13; no. 37
• Main Authors: Lei, Tianyu, Xie, Yiming, Wang, Xianfu, Miao, Shengyi, Xiong, Jie, Yan, Chenglin
• Format: Journal Article
• Language: English
• Published: Germany 01.10.2017
• Subjects: polysulfides restrictor; enhanced kinetics; TiO2 feather duster; Li-S batteries
• ISSN: 1613-6810; 1613-6829
• DOI: 10.1002/smll.201701013

The rechargeable lithium-sulfur battery is recognized as a promising candidate for electrochemical energy storage system because of their exceptional advance in energy density. However, the fast capacity decay of sulfur cathode caused by polysulfide dissolution and low specific capacity caused by poor electrical conductivity still impede the further development of lithium-sulfur battery. To address above issues, this study reports the synthesis of feather duster-like TiO architecture by in situ growth of TiO nanowires on carbon cloth and further evaluates as sulfur host material. The strong chemical binding interaction between the polysulfides and TiO feather duster efficiently restrains the shuttle effect, leading to enhanced electrochemical kinetics. Besides, the in situ grown TiO NWs array also supply high surface for sulfur-loading and fast path for electron transfer and ion diffusion. As results, the novel CC/TiO /S composite cathode exhibits a high capacity of 608 mA h g at 1.0 C after 700 cycles corresponding to capacity decay as low as 0.045% per cycle with excellent Coulombic efficiency higher than 99.5%.