14C Release from TRIGA irradiated graphite

• Published in: Radiocarbon Vol. 60; no. 6; pp. 1819 - 1829
• Main Authors: Bucur, C, Ichim, C, Florea, I
• Format: Journal Article
• Language: English
• Published: New York, USA Cambridge University Press 01.12.2018
• Subjects: Anaerobic conditions; Carbon; Carbon 14; Graphite; Hydrocarbons; Irradiated Graphites; Leachates; Leaching; Submerging; VOCs; Volatile organic compounds; 14C; irradiated graphite; release rate
• ISSN: 0033-8222; 1945-5755
• DOI: 10.1017/RDC.2018.131

Leaching tests were carried out in aerobic and anaerobic conditions to assess the 14C released from TRIGA irradiated graphite. Both total 14C and inorganic and organic fractions in the leachant solutions were measured. The experimental results obtained from the leaching tests confirm the low 14C release rate in alkaline environment. Less than 2% of the total 14C inventory in the specimens subject to the leaching tests was released as dissolved species. Both inorganic and organic 14C species are released in alkaline conditions, with more inorganic 14C release under aerobic conditions (around 68% of the total 14C released was released as inorganic dissolved species), and more organic 14C species in anaerobic conditions (around 65% of the total 14C released was released as organic dissolved species). Both for anaerobic and aerobic conditions, the leaching rates are high in the first days of immersion and decrease after that, indicating a two stage process: an initial quick release (less than 9 × 10–02 % of inventory/day for the first 48 days) followed by a slower release rate (around 4 × 10–03 % of inventory/day).