WO2–N co-doped 2D Carbon nanosheets as multifunctional additives for enhancing the electrochemical hydrogen storage performance of Co2B

• Published in: International journal of hydrogen energy Vol. 87; pp. 1254 - 1260
• Main Authors: Su, Yugang, Chen, Jiajin, Li, Haobo, Li, Siqi, Tian, Fubo, Jia, Hongsheng, Li, Liang
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 18.10.2024
• Subjects: Co2B; Electrochemical hydrogen absorption and discharge; High efficiency catalysis; WO2–N co-doped; Co2B; WO2–N co-doped; Electrochemical hydrogen absorption and discharge; High efficiency catalysis
• ISSN: 0360-3199
• DOI: 10.1016/j.ijhydene.2024.09.126

Co2B, with its high theoretical hydrogen storage capacity, is a potential solid-state hydrogen storage material. However, its poor cycling life limits its practical application. In this work, in order to improve the cycling stability and reversibility of hydrogen absorption and desorption of Co2B, we propose to use WO2–N–C nanosheets as dopants to mix with Co2B, thereby enhancing its practical performance. Two-dimensional tungsten oxide-nitrogen-carbon (WO2–N–C) nanosheets was syntheized via a liquid-phase approach, using a tungstenate-polydopamine precursor followed by thermal treatment. Subsequently, these WO2–N–C nanosheets were compounded with cobalt boride (Co2B) particles through ball milling at various ratios of 1%, 3%, and 5%, which were confirmed by XRD (X-ray diffraction) and SEM (Scanning Electron Microscope) methods. Employing a comprehensive suite of electrochemical analyses, including corrosion potential measurements, polarization curves, step voltammetry, and electrochemical impedance spectroscopy (EIS), we found that the incorporation of WO2–N–C significantly enhances the corrosion resistance and electrochemical activity of Co2B. Furthermore, cyclic life tests revealed that the WO2–N–C-doped Co2B composites exhibit superior discharge capacities and capacity retention rates compared to pristine Co2B. Notably, the 3% WO2–N–C-doped Co2B composite demonstrated the optimal electrochemical performance, achieving a maximum discharge specific capacity of 555 mAh g−1 and maintaining 82% of its initial capacity after 50 cycles. Our findings underscore the dual role of WO2–N–C in not only augmenting the surface electrochemical activity of Co2B but also providing a protective surface layer, thereby enhancing its overall electrochemical performance. •WO2–N–C were compounded with Co2B particles via ball milling at optimized ratios.•WO2–N–C improves the corrosion resistance and electrochemical activity of Co2B.•WO2–N–C-doped Co2B exhibit better discharge capacities and capacity retention rates.