Synthesis and properties of flexible supercapacitor based on zinc-aluminum layered doubled hydroxide

• Published in: Journal of alloys and compounds Vol. 1009; p. 176925
• Main Authors: Hammood, Sajjad A., Al-Asadi, Ahmed S., Al-Mudhaffer, Mohammed F.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 25.12.2024
• Subjects: Flexible; Nanosheets; Supercapacitor; ZnAl-LDHs; Supercapacitor; Nanosheets; Flexible; ZnAl-LDHs
• ISSN: 0925-8388
• DOI: 10.1016/j.jallcom.2024.176925

A flexible, effective supercapacitor using zinc-aluminum-layered double hydroxides (Zn-Al LDHs) as an electrode material is reported. Nanosheets of Zn-Al LDHs were synthesized using a chemical bath deposition method, and they were present in a well-standing shape covering the complete area of the Al foil. The imaging of these nanosheets showed that their average thickness is between 60 and 80 nm, with a width and length average of 1.3 and 0.6 μm, respectively. These dimensions help to create the connection arrangements of sheets with a high specific surface area of 88 m2/g which increased electrochemical active sites for charge storage. The X-ray diffraction further approves the structural properties of the prepared material. The flexibility of the supercapacitor was examined by bending and folding up the device to 180° with little mechanical deformation. The highest capacitance value is found to be ∼597F/g in the case of the flat condition. The capacitance value decreased to ∼387F/g after folding the device 30°, and these values drooped slightly after more increasing the folding angle. The energy density (ED) remains nearly constant at any folding angle (ED=3.39Wh/kg at 30° and ED=3.7Wh/kg at 135°), and similarly, the power density (PD) remains nearly constant (PD=27 kW/kg at 30° and 135°). The aforementioned approves the flexibility of the Zn-Al LHD because it provides lifelong stability (87 % retaining after 2000 charge/discharge cycles) and stable efficiency after different bending and twisting conditions. The impedance measurements along with the obtained equivalent circuits confirm the electrical characteristics of the as-prepared electrodes with low equivalent series resistances, ensuing the promising conductive path in the supercapacitor device. [Display omitted] •Zn-Al LDHs@Al foil was fabricated using one-step chemical bath deposition method.•Zn-Al LDHs nanosheets @ Al foil offered an effective surface area of 88m2/g.•Flexible supercapacitor was designed and evaluated in flat/bend/twist conditions.•The Zn-Al LDHs@Al electrode results in a maximum specific capacitance of 597 F/g.•The as-prepared electrode exhibits a well-standard performance in flat and other conditions.