An Efficient Gram Scale Synthesis of Aryl Iodides from Aryl Diazofluoroborates in Water Under Mild Conditions

Transition metal-free synthesis of synthetically valuable aryl iodides from aryl diazofluroborates in water under mild conditions has been described. Majority of synthesized aryl iodides are obtained in quantitative yields (>99 %) under present reaction conditions. The structural effects due to t...

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Bibliographic Details
Published inLetters in organic chemistry Vol. 15; no. 7; pp. 594 - 599
Main Author Gholap, Somnath S.
Format Journal Article
LanguageEnglish
Published SHARJAH Bentham Science Publ Ltd 13.06.2018
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ACID
AROMATIC IODINATION
CATALYST
GREEN
ARYLDIAZONIUM TETRAFLUOROBORATE SALTS
diazofluoroborates
quantitative protocol
Aryl iodides
DIAZONIUM TETRAFLUOROBORATE
AMINES
CHEMISTRY
CHLORIDES
transition metal-free
organic
potassium iodide
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Summary:Transition metal-free synthesis of synthetically valuable aryl iodides from aryl diazofluroborates in water under mild conditions has been described. Majority of synthesized aryl iodides are obtained in quantitative yields (>99 %) under present reaction conditions. The structural effects due to the substituents present on aryl diazofluoroborates did not show any satisfactory effect on the yields of the aryl iodides. Hence, the methodology presented here was found to be adventitious for the quantitative production of synthetically valuable aryl iodides.
ISSN:1570-1786
1875-6255
DOI:10.2174/1570178614666170907120329