New Procedure for the Highly Regioselective Aerobic Bromination of Aromatic Compounds Using Copper-based Nanocatalyst

A new procedure for the highly regioselective aerobic bromination of aromatic compounds in the presence of copper-based nanoparticles (CuO/ZnO nanocatalyst) under reflux condition is described. Mechanistic parameters are discussed and the plausible mechanism is proposed. Recyclability of the CuO/ZnO...

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Bibliographic Details
Published inLetters in organic chemistry Vol. 17; no. 3; pp. 234 - 239
Main Authors Albadi, Jalal, Jalali, Mehdi
Format Journal Article
LanguageEnglish
Published SHARJAH Bentham Science Publ Ltd 01.01.2020
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
REAGENT
potassium bromide
POTASSIUM-BROMIDE
aromatic compounds
IODINATION
HALOGENATION
regioselective
CuO/ZnO nanocatalyst
OXIDATIVE BROMINATION
ALCOHOLS
ANILINES
OXIDE NANOCATALYST
RECYCLABLE CATALYST
EFFICIENT
Aerobic catalysis
bromination
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Summary:A new procedure for the highly regioselective aerobic bromination of aromatic compounds in the presence of copper-based nanoparticles (CuO/ZnO nanocatalyst) under reflux condition is described. Mechanistic parameters are discussed and the plausible mechanism is proposed. Recyclability of the CuO/ZnO nanocatalyst has also been explored upon aerobic bromination of aromatic compounds.
ISSN:1570-1786
1875-6255
DOI:10.2174/1570178616666190429145952