Ultrahigh electrostrain > 1% in lead-free piezoceramics: A critical review

• Published in: arXiv.org
• Main Authors: Gobinda Das Adhikary, Digivijay Narayan Singh, Getaw, Abebe Tina, Muleta, Gudeta Jafo, Ranjan, Rajeev
• Format: Paper Journal Article
• Language: English
• Published: Ithaca Cornell University Library, arXiv.org 06.06.2023
• Subjects: Bismuth titanate; Composition; Defects; Diameters; Dipoles; Electric fields; Lead free; Physics - Materials Science; Piezoelectric ceramics; Thickness
• ISSN: 2331-8422
• DOI: 10.48550/arxiv.2306.03343

Recently, a series of reports showing ultra-high electrostrain (> 1 %) have appeared in several Pb-free piezoceramics. The ultrahigh electrostrain has been attributed exclusively to the defect dipoles created in these systems. We examine these claims based on another report arXiv:2208.07134 which demonstrated that the measured electric field driven strain increased dramatically simply by reducing the thickness of the ceramic discs. We prepared some representative Pb-free compositions reported to exhibit ultrahigh strain and performed electrostrain measurements. We found that these compositions do not show ultrahigh electrostrain if the thickness of the discs is above 0.3 mm (the disc diameters were in the range 10- 12 mm diameter). The ultrahigh strain values were obtained when the thickness was below 0.3 mm. We compare the electrostrain obtained from specimens designed to exhibit defect dipoles with specimens that were not designed to have defect dipoles in Na0.5Bi0.5TiO3 (NBT) and K0.5Na0.5NbO3 (KNN) -based lead-free systems and could obtain much higher strain levels (4- 5 %) in the defect dipole free piezoceramics in the small thickness regime. Our results do not favor the defect dipole theory as the exclusive factor for causing ultrahigh strain in piezoceramics. A new approach is called for to understand the phenomenon of ultrahigh electrostrain caused by the thickness reduction of piezoceramic discs.