Measurements of Pressure-Broadening Coefficients for the F‘ = 3 ← F‘ ‘ = 4 Hyperfine Line of the 2P1/2 ← 2P3/2 Transition in Atomic Iodine

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 106; no. 36; pp. 8323 - 8327
• Main Authors: Davis, S. J, Mulhall, P. A, Bachman, M, Kessler, W. J, Keating, P. B
• Format: Journal Article
• Language: English
• Published: American Chemical Society 12.09.2002
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/jp014690k

We describe a series of measurements of pressure-broadening coefficients for the F‘ = 3 ← F‘ ‘ = 4 line of the 2P1/2 ← 2P3/2 transition in atomic iodine. This is the optical transition of the chemically pumped atomic iodine laser (COIL), and our results are relevant to a more complete understanding of this important class of high-power lasers. The measurements were made in sealed cells using an argon ion laser to photodissociate molecular iodine and a tunable diode laser to probe directly the atomic transition. We measured broadening coefficients for three bath gases:  He, N2, and O2. Full absorption line shapes were recorded as a function of the added bath gas pressure and the following values were obtained at room temperature:  (Δν/ΔP He) T =296K = 3.2 ± 0.3 MHz/Torr, (Δν/ΔP N 2) T =296 K = 5.5 ± 0.6 MHz/Torr, and (Δν/ΔP O 2) T =296 K = 5.0 ± 0.5 MHz/Torr; where Δν is the full width at half-maximum. We also measured the temperature dependencies of the He and O2 broadening coefficients over the range 296 K < T < 775 K. We quote the temperature-dependent values as (Δν/ΔP He) T = (3.2 ± 0.3) × (296/T)0.36 and (Δν/ΔP O 2) T = (5.5 ± 0.6) × (296/T)0.70. Comparisons to previous measurements are also discussed.