Stockmayer supracolloidal magnetic polymers under the influence of an applied magnetic field and a shear flow
The idea of creating magnetically controllable colloids whose rheological properties can be finely tuned on the nano- or micro-scale has caused a lot of experimental and theoretical effort. The latter resulted in systems whose building blocks are ranging between single magnetic nanoparticles to comp...
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Main Authors | , , , |
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Format | Journal Article |
Language | English |
Published |
05.06.2023
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Subjects | |
Online Access | Get full text |
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Summary: | The idea of creating magnetically controllable colloids whose rheological
properties can be finely tuned on the nano- or micro-scale has caused a lot of
experimental and theoretical effort. The latter resulted in systems whose
building blocks are ranging between single magnetic nanoparticles to complexes
of such nanoparticles bound together by various mechanisms. The binding can be
either chemical or physical, reversible or not. One way to create a system that
is physically bound is to let the precrosslinked supracolloidal magnetic
polymers (SMPs) to cluster due to both magnetic and Van-der-Waals-type forces.
The topology of the SMPs in this case can be used to tune both magnetic and
rheological properties of the resulting clusters as we show in this work. We
employ Molecular Dynamics computer simulations coupled with explicit solvent
modelled by Lattice-Boltzmann method in order to model the behaviour of the
clusters formed by chains, rings, X- and Y-shaped SMPs in a shear flow with
externally applied magnetic field. We find that the shear stabilises the shape
of the clusters not letting them extend in the direction of the field and
disintegrate. The clusters that show the highest response to an applied field
and higher shape stability are those made of Y- and X-like SMPs. |
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DOI: | 10.48550/arxiv.2306.03005 |