Theoretical and Experimental Study of Compression Effects on Structural Relaxation of Glass-Forming Liquids

We develop the elastically collective nonlinear Langevin equation theory of bulk relaxation of glass-forming liquids to investigate molecular mobility under compression conditions. The applied pressure restricts more molecular motion and therefore significantly slows down the molecular dynamics when...

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Bibliographic Details
Published inACS omega Vol. 5; no. 19; pp. 11035 - 11042
Main Authors Phan, Anh D, Jedrzejowska, Agnieszka, Paluch, Marian, Wakabayashi, Katsunori
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 19.05.2020
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Summary:We develop the elastically collective nonlinear Langevin equation theory of bulk relaxation of glass-forming liquids to investigate molecular mobility under compression conditions. The applied pressure restricts more molecular motion and therefore significantly slows down the molecular dynamics when increasing the pressure. We quantitatively determine the temperature and pressure dependence of the structural relaxation time. To validate our model, dielectric spectroscopy experiments for three rigid and nonpolymeric supramolecules are carried out at ambient and elevated pressures. The numerical results quantitatively agree with experimental data.
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ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.0c00860