Topological Quantum Materials from the Viewpoint of Chemistry

• Published in: Chemical reviews Vol. 121; no. 5; pp. 2780 - 2815
• Main Authors: Kumar, Nitesh, Guin, Satya N, Manna, Kaustuv, Shekhar, Chandra, Felser, Claudia
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 10.03.2021
• Subjects: Chemical bonds; Chemistry; Condensed matter physics; Crystal growth; Crystals; Electrons; Fermi surfaces; Materials science; Measurement techniques; Metalloids; Review; Single crystals; Solid state; Spin-orbit interactions; Topological insulators; Topology; Valence band
• ISSN: 0009-2665; 1520-6890
• DOI: 10.1021/acs.chemrev.0c00732

Topology, a mathematical concept, has recently become a popular and truly transdisciplinary topic encompassing condensed matter physics, solid state chemistry, and materials science. Since there is a direct connection between real space, namely atoms, valence electrons, bonds, and orbitals, and reciprocal space, namely bands and Fermi surfaces, via symmetry and topology, classifying topological materials within a single-particle picture is possible. Currently, most materials are classified as trivial insulators, semimetals, and metals or as topological insulators, Dirac and Weyl nodal-line semimetals, and topological metals. The key ingredients for topology are certain symmetries, the inert pair effect of the outer electrons leading to inversion of the conduction and valence bands, and spin–orbit coupling. This review presents the topological concepts related to solids from the viewpoint of a solid-state chemist, summarizes techniques for growing single crystals, and describes basic physical property measurement techniques to characterize topological materials beyond their structure and provide examples of such materials. Finally, a brief outlook on the impact of topology in other areas of chemistry is provided at the end of the article.