Solid-State NMR Spectroscopy of Molecular Hydrogen Trapped Inside an Open-Cage Fullerene

Solid-state 1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measuremen...

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 126; no. 13; pp. 4092 - 4093
Main Authors Carravetta, Marina, Murata, Yasujiro, Murata, Michihisa, Heinmaa, Ivo, Stern, Raivo, Tontcheva, Ana, Samoson, Ago, Rubin, Yves, Komatsu, Koichi, Levitt, Malcolm H
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 07.04.2004
Subjects
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
Magnetic resonances and relaxations in condensed matter, mössbauer effect
Nuclear magnetic resonance and relaxation
Physics
Relaxation effects
Encapsulation
Solid state
Chemical shift
Fullerene compounds
NMR parameter
Spin-lattice relaxation
Spin-spin relaxation
Hydrogen molecules
Experimental study
NMR spectroscopy
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Summary:Solid-state 1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measurements as a function of temperature.
Bibliography:istex:3409E981E3C8E3CF0D3E47E3B2530C1159A1A834
ark:/67375/TPS-CHJN0GKQ-Z
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0002-7863
1520-5126
DOI:10.1021/ja031536y