Pressure-induced Spin-Peierls to Incommensurate Charge-Density-Wave Transition in the Ground State of TiOCl
The ground state of the spin-Peierls system TiOCl was probed using synchrotron x-ray diffraction on a single-crystal sample at T = 6 K. We tracked the evolution of the structural superlattice peaks associated with the dimerized ground state as a function of pressure. The dimerization along the b axi...
Saved in:
Published in | arXiv.org |
---|---|
Main Authors | , , , |
Format | Paper Journal Article |
Language | English |
Published |
Ithaca
Cornell University Library, arXiv.org
04.08.2009
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | The ground state of the spin-Peierls system TiOCl was probed using synchrotron x-ray diffraction on a single-crystal sample at T = 6 K. We tracked the evolution of the structural superlattice peaks associated with the dimerized ground state as a function of pressure. The dimerization along the b axis is rapidly suppressed in the vicinity of a first-order structural phase transition at Pc = 13.1(1) GPa. The high-pressure phase is characterized by an incommensurate charge density wave perpendicular to the original spin chain direction. These results show that the electronic ground state undergoes a fundamental change in symmetry, indicating a significant change in the principal interactions. |
---|---|
ISSN: | 2331-8422 |
DOI: | 10.48550/arxiv.0908.0518 |