Interplay of Wrinkles, Strain, and Lattice Parameter in Graphene on Iridium

• Published in: Nano letters Vol. 12; no. 2; pp. 678 - 682
• Main Authors: Hattab, Hichem, N’Diaye, Alpha T, Wall, Dirk, Klein, Claudius, Jnawali, Giriraj, Coraux, Johann, Busse, Carsten, van Gastel, Raoul, Poelsema, Bene, Michely, Thomas, Meyer zu Heringdorf, Frank-J, Horn-von Hoegen, Michael
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 08.02.2012
• Subjects: Compressive properties; Condensed Matter; Condensed matter: structure, mechanical and thermal properties; Ethylene; Exact sciences and technology; Formations; Graphene; Graphite - chemistry; Guidelines; Iridium - chemistry; Kinetics; Lattice parameters; Materials Science; Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals; Particle Size; Physics; Spots; Strain; Strategy; Structure of solids and liquids; crystallography; Surface Properties; Temperature; iridium; strain state; wrinkle formation; LEED; Graphene; Compressive stress; Thermal decomposition; Strained layer; Moire fringes; Kinetics; High temperature; Lattice parameters; Defects
• ISSN: 1530-6984; 1530-6992
• DOI: 10.1021/nl203530t

Following graphene growth by thermal decomposition of ethylene on Ir(111) at high temperatures we analyzed the strain state and the wrinkle formation kinetics as function of temperature. Using the moiré spot separation in a low energy electron diffraction pattern as a magnifying mechanism for the difference in the lattice parameters between Ir and graphene, we achieved an unrivaled relative precision of ±0.1 pm for the graphene lattice parameter. Our data reveals a characteristic hysteresis of the graphene lattice parameter that is explained by the interplay of reversible wrinkle formation and film strain. We show that graphene on Ir(111) always exhibits residual compressive strain at room temperature. Our results provide important guidelines for strategies to avoid wrinkling.