Metal–Organic Frameworks against Toxic Chemicals

Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly....

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Published inChemical reviews Vol. 120; no. 16; pp. 8130 - 8160
Main Authors Islamoglu, Timur, Chen, Zhijie, Wasson, Megan C, Buru, Cassandra T, Kirlikovali, Kent O, Afrin, Unjila, Mian, Mohammad Rasel, Farha, Omar K
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 26.08.2020
Subjects
Adsorbents
Ammonia
Blistering
carbon monoxide
Cations
Chemical warfare
Chemicals
Chemistry
coordination polymers
Hydrogen sulfide
metal ions
Metal-organic frameworks
nerve agents
Nitrogen dioxide
Self-assembly
Sulfur dioxide
toxicity
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Summary:Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal–organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.
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USDOE Office of Science (SC)
FG02-08ER15967
ISSN:0009-2665
1520-6890
1520-6890
DOI:10.1021/acs.chemrev.9b00828