Enantioselective Synthesis of Nonracemic Geminal Silylboronates by Pt-Catalyzed Hydrosilylation

A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral nonracemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.

Saved in:
Bibliographic Details
Published inACS catalysis Vol. 8; no. 4; pp. 2897 - 2901
Main Authors Szymaniak, Adam A, Zhang, Chenlong, Coombs, John R, Morken, James P
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 06.04.2018
Subjects
hydrosilylation
catalysis
silicon
asymmetric
boron
If you are submitting your paper to a journal that requires keywords
provide significant keywords to aid the reader in literature retrieval
Online AccessGet full text

Cover

More Information
Summary:A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral nonracemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
The manuscript was written through contributions of all authors.
AUTHOR INFORMATION
Author Contributions
ISSN:2155-5435
2155-5435
DOI:10.1021/acscatal.8b00221