Facile Fabrication of ZnMgAl/LDH/Algae Composites as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and Equilibrium Studies

• Published in: ACS omega Vol. 5; no. 48; pp. 31342 - 31351
• Main Authors: Said, Ibrahim, Abukhadra, Mostafa R, Rabie, Abdelrahman M, Bakr, Al-Sayed A, Shim, Jae-Jin, Ahmed, Sayed Abdelkader
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 08.12.2020
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.0c04842

In order to improve the adsorption capacity of natural layered double hydroxyl (LDH) materials, the natural organic sources such as algae containing hydroxyl groups, amino groups, peptide connections, and alginate structures were used to improve LDH for the preparation of ZnMgAl LDH-algae composites (LDH-Ax). The structure of prepared composites was established and characterized via various techniques such as scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The LDH-A2 sample displayed the highest efficiency for Cr­(VI) removal, which reached to 99% at the optimum conditions. The prepared composite LDH-A2 showed high stability and reusability (91.7%) after five cycles. The kinetic studies revealed that the Cr uptake by LDH-A1 is described as pseudo-first order, while the case of LDH-A2 is described as pseudo-second order. This study reported that the easily synthesized LDH-Ax has an interesting environmental approval process to eliminate Cr ions from aqueous media quickly and effectively.