Preparation of Nanoscale Semi-IPNs with an Interconnected Microporous Structure via Cationic Polymerization of Bio-Based Tung Oil in a Homogeneous Solution of Poly(ε-caprolactone)
Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic polymerization and compatibilization in a homogeneous solution. This novel blending technique produced a nanoscale morphology of poly(ε-caprolac...
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| Published in | ACS omega Vol. 5; no. 17; pp. 9977 - 9984 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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American Chemical Society
05.05.2020
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| Abstract | Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic polymerization and compatibilization in a homogeneous solution. This novel blending technique produced a nanoscale morphology of poly(ε-caprolactone) with average particle sizes as small as 100 nm dispersed in a cross-linked tung oil matrix for 20 and 30 wt % PCL blend compositions. In addition, the exothermic cationic polymerization of tung oil in the presence of the PCL homogeneous solution created a microporous morphology with open three-dimensional interconnected cluster structures. The porous morphology was found to be composition-dependent (the pore size and interconnectivity decreased with increasing PCL content in the blend). The values of the cross-link density and storage modulus in the glassy state for fully cured samples increased significantly and reached a maximum for the 20 wt % PCL blend. This simple, versatile, low-cost strategy for preparing nanoscale and interconnected three-dimensional cluster structures with a microporous morphology and desired properties should be widely applicable for new polymer systems. |
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| AbstractList | Nanoscale semi-interpenetrating
polymer networks of bio-based poly(ε-caprolactone)
(PCL) and polymerized tung oil have been prepared via in situ cationic
polymerization and compatibilization in a homogeneous solution. This
novel blending technique produced a nanoscale morphology of poly(ε-caprolactone)
with average particle sizes as small as 100 nm dispersed in a cross-linked
tung oil matrix for 20 and 30 wt % PCL blend compositions. In addition,
the exothermic cationic polymerization of tung oil in the presence
of the PCL homogeneous solution created a microporous morphology with
open three-dimensional interconnected cluster structures. The porous
morphology was found to be composition-dependent (the pore size and
interconnectivity decreased with increasing PCL content in the blend).
The values of the cross-link density and storage modulus in the glassy
state for fully cured samples increased significantly and reached
a maximum for the 20 wt % PCL blend. This simple, versatile, low-cost
strategy for preparing nanoscale and interconnected three-dimensional
cluster structures with a microporous morphology and desired properties
should be widely applicable for new polymer systems. Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic polymerization and compatibilization in a homogeneous solution. This novel blending technique produced a nanoscale morphology of poly(ε-caprolactone) with average particle sizes as small as 100 nm dispersed in a cross-linked tung oil matrix for 20 and 30 wt % PCL blend compositions. In addition, the exothermic cationic polymerization of tung oil in the presence of the PCL homogeneous solution created a microporous morphology with open three-dimensional interconnected cluster structures. The porous morphology was found to be composition-dependent (the pore size and interconnectivity decreased with increasing PCL content in the blend). The values of the cross-link density and storage modulus in the glassy state for fully cured samples increased significantly and reached a maximum for the 20 wt % PCL blend. This simple, versatile, low-cost strategy for preparing nanoscale and interconnected three-dimensional cluster structures with a microporous morphology and desired properties should be widely applicable for new polymer systems. Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic polymerization and compatibilization in a homogeneous solution. This novel blending technique produced a nanoscale morphology of poly(ε-caprolactone) with average particle sizes as small as 100 nm dispersed in a cross-linked tung oil matrix for 20 and 30 wt % PCL blend compositions. In addition, the exothermic cationic polymerization of tung oil in the presence of the PCL homogeneous solution created a microporous morphology with open three-dimensional interconnected cluster structures. The porous morphology was found to be composition-dependent (the pore size and interconnectivity decreased with increasing PCL content in the blend). The values of the cross-link density and storage modulus in the glassy state for fully cured samples increased significantly and reached a maximum for the 20 wt % PCL blend. This simple, versatile, low-cost strategy for preparing nanoscale and interconnected three-dimensional cluster structures with a microporous morphology and desired properties should be widely applicable for new polymer systems. |
| Author | Madbouly, Samy A Kessler, Michael R |
| AuthorAffiliation | Department of Chemistry, Faculty of Science Department of Mechanical Engineering North Dakota State University School of Engineering Cairo University |
| AuthorAffiliation_xml | – name: School of Engineering – name: Department of Mechanical Engineering – name: Department of Chemistry, Faculty of Science – name: North Dakota State University – name: Cairo University |
| Author_xml | – sequence: 1 givenname: Samy A orcidid: 0000-0002-4903-4362 surname: Madbouly fullname: Madbouly, Samy A email: sum1541@psu.edu organization: Cairo University – sequence: 2 givenname: Michael R orcidid: 0000-0001-8436-3447 surname: Kessler fullname: Kessler, Michael R organization: North Dakota State University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32391485$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1007_s10973_023_12368_x crossref_primary_10_1371_journal_pone_0237691 crossref_primary_10_3390_polym15030564 crossref_primary_10_1016_j_ijbiomac_2020_08_095 crossref_primary_10_1016_j_cej_2024_150863 crossref_primary_10_1016_j_indcrop_2020_112886 crossref_primary_10_1177_1045389X241233810 crossref_primary_10_3390_polym13111722 |
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| Snippet | Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic... Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic... Nanoscale semi-interpenetrating polymer networks of bio-based poly(ε-caprolactone) (PCL) and polymerized tung oil have been prepared via in situ cationic... |
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| Title | Preparation of Nanoscale Semi-IPNs with an Interconnected Microporous Structure via Cationic Polymerization of Bio-Based Tung Oil in a Homogeneous Solution of Poly(ε-caprolactone) |
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