Transparent, Superflexible Doubly Cross-Linked Polyvinylpolymethylsiloxane Aerogel Superinsulators via Ambient Pressure Drying

• Published in: ACS nano Vol. 12; no. 1; pp. 521 - 532
• Main Authors: Zu, Guoqing, Shimizu, Taiyo, Kanamori, Kazuyoshi, Zhu, Yang, Maeno, Ayaka, Kaji, Hironori, Shen, Jun, Nakanishi, Kazuki
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 23.01.2018
• Subjects: ultralow cost; superflexible; polyvinylpolymethylsiloxane aerogel; superinsulating; transparent
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.7b07117

Aerogels have many attractive properties but are usually costly and mechanically brittle, which always limit their practical applications. While many efforts have been made to reinforce the aerogels, most of the reinforcement efforts sacrifice the transparency or superinsulating properties. Here we report superflexible polyvinylpolymethylsiloxane, (CH2CH­(Si­(CH3)­O2/2)) n , aerogels that are facilely prepared from a single precursor vinylmethyldimethoxysilane or vinylmethyldiethoxysilane without organic cross-linkers. The method is based on consecutive processes involving radical polymerization and hydrolytic polycondensation, followed by ultralow-cost, highly scalable, ambient-pressure drying directly from alcohol as a drying medium without any modification or additional solvent exchange. The resulting aerogels and xerogels show a homogeneous, tunable, highly porous, doubly cross-linked nanostructure with the elastic polymethylsiloxane network cross-linked with flexible hydrocarbon chains. An outstanding combination of ultralow cost, high scalability, uniform pore size, high surface area, high transparency, high hydrophobicity, excellent machinability, superflexibility in compression, superflexibility in bending, and superinsulating properties has been achieved in a single aerogel or xerogel. This study represents a significant progress of porous materials and makes the practical applications of transparent flexible aerogel-based superinsulators realistic.