Hydrochemistry of groundwaters in a spa area of Korea: an implication for water quality degradation by intensive pumping

• Published in: Hydrological processes Vol. 19; no. 2; pp. 493 - 505
• Main Authors: Kim, Kangjoo, Koo, Min-Ho, Moon, Sang-Ho, Yum, Byoung-Woo, Lee, Kwang-Sik
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Ltd 15.02.2005; Wiley
• Subjects: Earth sciences; Earth, ocean, space; Exact sciences and technology; fluoride; Geochemistry; geothermal water; heavy pumping; Hydrogeology; Hydrology. Hydrogeology; Isotope geochemistry; Isotope geochemistry. Geochronology; Mineralogy; mixing; Onyang Spa; Silicates; Water geochemistry; water-quality degradation; Far East; South Korea; Korea; Korea, Rep; O-18/O-16; fluorides; mixing; heavy pumping; ground water; Onyang Spa; fluoride; degradation; nitrates; human activity; geothermal water; aquifers; hydrochemistry; thermal waters; fractures; stable isotopes; models; solutes; water-quality degradation; concentration; pressure; halides; chemical analysis; intrusions; contamination; pumping; water quality; Asia
• ISSN: 0885-6087; 1099-1085
• DOI: 10.1002/hyp.5551

A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m3 year−1) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.