Catalytic Palladium-Based and Iron-Based Membrane Reactors: Novel Strategies of Synthesis

Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal a...

Full description

Saved in:
Bibliographic Details
Published inACS omega Vol. 4; no. 22; pp. 19818 - 19828
Main Authors Pinos-Vélez, Verónica, di Luca, Carla, Crivoi, Dana G, Medina, Francisco, Dafinov, Anton
Format Journal Article
LanguageEnglish
Published American Chemical Society 26.11.2019
Online AccessGet full text

Cover

More Information
Summary:Several procedures were employed in the preparation of different Pd- and Fe-based catalytic membrane reactors (CMRs) via the normal wet impregnation method, reverse filtration of a microemulsion, sputtering method, and the precipitation of a Fe complex. Depending on the chosen procedure, the metal active phase can be found on the exterior and/or interior part of the CMR or even in its pores in concentrations between 0.05 and 2 wt %. Moreover, we have managed to implement a unique systematic process to grow hydrotalcite in the pores of a Pd-CMR. To exemplify the activity of these new CMRs, we have tested them in the peroxidation of phenol and in situ epoxidation of trans-chalcone.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.9b02706