Removal of CO Generated by a Gas Explosion Using a Cu–Mn Elimination Agent

• Published in: ACS omega Vol. 6; no. 24; pp. 16140 - 16150
• Main Authors: Sun, Yashengnan, Zhou, Xihua, Bai, Gang, Teng, Yifei, Xin, Tianyu, Xiao, Mufeng
• Format: Journal Article
• Language: English
• Published: American Chemical Society 22.06.2021
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.1c02019

Addressing the issue of suffocation and casualties caused by a large amount of poisonous CO gas generated after a gas explosion, research involving an experimental system for the removal of CO using a Cu–Mn elimination agent was studied. The influence of O2 concentration, temperature, and CO concentration on the elimination performance of the agent after a gas explosion was studied. The quantitative relationship between the amount of CO eliminated, the elimination rate, the O2 concentration, and temperature was analyzed. Further analysis was completed regarding the influence of O2 concentration, temperature, and CO concentration on the thermal effect in the elimination process. The results showed that the elimination agent had a rapid effect on the removal of CO. When the ratio of CO concentration to O2 concentration was closer to the stoichiometric ratio, the elimination and reaction were more complete, the time to complete elimination was shorter, and the peak temperature was higher. As the temperature increased, the time to reach the elimination limit became longer, the elimination rate decreased, the reaction was slower, and the peak temperature was lower. As the CO concentration increased, it was observed that the higher the peak temperature, the longer it took to reach the peak time. The results of the study provide a theoretical support for the catalytic oxidation of CO using the Cu–Mn eliminator after a coal mine gas explosion.