Large Physisorption Strain in Chemical Vapor Deposition of Graphene on Copper Substrates

Graphene single layers grown by chemical vapor deposition on single crystal Cu substrates are subject to nonuniform physisorption strains that depend on the orientation of the Cu surface. The strains are revealed in Raman spectra and quantitatively interpreted by molecular dynamics (MD) simulations....

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Published inNano letters Vol. 12; no. 5; pp. 2408 - 2413
Main Authors He, Rui, Zhao, Liuyan, Petrone, Nicholas, Kim, Keun Soo, Roth, Michael, Hone, James, Kim, Philip, Pasupathy, Abhay, Pinczuk, Aron
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 09.05.2012
Subjects
CHEMICAL VAPOR DEPOSITION
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Compressive properties
COMPUTER SIMULATION
Copper
Cross-disciplinary physics: materials science; rheology
DEPOSITION
Exact sciences and technology
Fullerenes and related materials; diamonds, graphite
Graphene
Materials science
Methods of deposition of films and coatings; film growth and epitaxy
MICA
MICROSTRUCTURES
Molecular dynamics
Nanostructure
Nonuniform
Physics
PROPERTIES
Simulation
Specific materials
STRAIN
VAPOR DEPOSITION
CVD
strain
copper
Graphene
Monocrystals
Digital simulation
Molecular dynamics method
Theoretical study
Copper
Raman spectroscopy
Physisorption
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Abstract Graphene single layers grown by chemical vapor deposition on single crystal Cu substrates are subject to nonuniform physisorption strains that depend on the orientation of the Cu surface. The strains are revealed in Raman spectra and quantitatively interpreted by molecular dynamics (MD) simulations. An average compressive strain on the order of 0.5% is determined in graphene on Cu(111). In graphene on Cu (100), MD simulations interpret the observed highly nonuniform strains.
AbstractList Graphene single layers grown by chemical vapor deposition on single crystal Cu substrates are subject to nonuniform physisorption strains that depend on the orientation of the Cu surface. The strains are revealed in Raman spectra and quantitatively interpreted by molecular dynamics (MD) simulations. An average compressive strain on the order of 0.5% is determined in graphene on Cu(111). In graphene on Cu (100), MD simulations interpret the observed highly nonuniform strains.
Graphene single layers grown by chemical vapor deposition on single crystal Cu substrates are subject to nonuniform physisorption strains that depend on the orientation of the Cu surface. The strains are revealed in Raman spectra and quantitatively interpreted by molecular dynamics (MD) simulations. An average compressive strain on the order of 0.5% is determined in graphene on Cu(111). In graphene on Cu (100), MD simulations interpret the observed highly nonuniform strains.Graphene single layers grown by chemical vapor deposition on single crystal Cu substrates are subject to nonuniform physisorption strains that depend on the orientation of the Cu surface. The strains are revealed in Raman spectra and quantitatively interpreted by molecular dynamics (MD) simulations. An average compressive strain on the order of 0.5% is determined in graphene on Cu(111). In graphene on Cu (100), MD simulations interpret the observed highly nonuniform strains.
Author He, Rui
Petrone, Nicholas
Hone, James
Pasupathy, Abhay
Pinczuk, Aron
Kim, Keun Soo
Zhao, Liuyan
Kim, Philip
Roth, Michael
AuthorAffiliation University of Northern Iowa
Sejong University
Columbia University
AuthorAffiliation_xml – name: University of Northern Iowa
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– name: Columbia University
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  givenname: Rui
  surname: He
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  fullname: Zhao, Liuyan
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  surname: Petrone
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strain
copper
Graphene
Monocrystals
Digital simulation
Molecular dynamics method
Theoretical study
Copper
Raman spectroscopy
Physisorption
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Snippet Graphene single layers grown by chemical vapor deposition on single crystal Cu substrates are subject to nonuniform physisorption strains that depend on the...
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SubjectTerms CHEMICAL VAPOR DEPOSITION
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Compressive properties
COMPUTER SIMULATION
Copper
Cross-disciplinary physics: materials science; rheology
DEPOSITION
Exact sciences and technology
Fullerenes and related materials; diamonds, graphite
Graphene
Materials science
Methods of deposition of films and coatings; film growth and epitaxy
MICA
MICROSTRUCTURES
Molecular dynamics
Nanostructure
Nonuniform
Physics
PROPERTIES
Simulation
Specific materials
STRAIN
VAPOR DEPOSITION
Title Large Physisorption Strain in Chemical Vapor Deposition of Graphene on Copper Substrates
URI http://dx.doi.org/10.1021/nl300397v
https://www.ncbi.nlm.nih.gov/pubmed/22494089
https://www.proquest.com/docview/1012208502
https://www.proquest.com/docview/1762050665
Volume 12
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