Preparation of Vinyl Silyl Ethers and Disiloxanes via the Silyl-Heck Reaction of Silyl Ditriflates

Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vi...

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 135; no. 36; pp. 13330 - 13333
Main Authors Martin, Sara E. S., Watson, Donald A.
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 11.09.2013
Amer Chemical Soc
Subjects
Alkenes - chemistry
Chemistry
Chemistry, Multidisciplinary
Ethers - chemical synthesis
Ethers - chemistry
Molecular Structure
Physical Sciences
Science & Technology
Silanes - chemical synthesis
Silanes - chemistry
Vinyl Compounds - chemical synthesis
Vinyl Compounds - chemistry
ALKENES
CROSS-COUPLING REACTIONS
SILICON
SUBSTITUENTS
OLEFINS
VINYLSILANES
METATHESIS
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Summary:Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.
Bibliography:NIH RePORTER
National Science Foundation
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja407748z