Microstructural and Sensitivity Changes of Neat, Spray-Dried RDX

• Published in: ACS omega Vol. 8; no. 1; pp. 1514 - 1522
• Main Authors: Tisdale, Jeremy T., Scott, Brian L., Freye, Chris E., Hill, Larry G., Duque, Amanda L.
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 10.01.2023
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.2c07011

Spray drying has recently gained interest in the high explosives (HE) community for the production of novel nanocomposites and well-controlled particle size distributions. However, there is a dearth of information on spray-dried, neat energetic materials. In this work, we correlate the spray drying production parameters to the resulting microstructure and handling sensitivity properties of neat RDX. We demonstrate the capability to fine-tune the particle size distributions for “nanopowder” spray-dried RDX, as well as larger particle size distributions by simply changing the spray dryer setup. We also investigate other physical and chemical changes that RDX undergoes after being processed with spray drying. We characterize these changes with scanning electron microscopy, X-ray diffraction, ultrahigh-performance liquid chromatography, and small-scale sensitivity tests. Interestingly, although the phase and chemical properties are similar before and after spray drying, small-scale sensitivity testing reveals that size reduction of RDX does not follow the typical HE desensitization trends, generally observed for other energetic materials.