A Favorable Case Where an Experimental Electron Density Analysis Offers a Lead for Understanding a Specific Fluxional Process Observed in Solution

A topological analysis of the electron density in the ketene complex (η5-MeC5H4)(CO)2Mn[η2-OCC((μ-η2-C⋮CPh)Co2(CO)6)Ph] indicates a predisposition for the carbene component of the ketene ligand to bind the neighboring C atom of the adjacent CO ligand.

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Bibliographic Details
Published inInorganic chemistry Vol. 44; no. 26; pp. 9607 - 9609
Main Authors Ortin, Yannick, Lugan, Noël, Pillet, Sébastien, Souhassou, Mohammed, Lecomte, Claude, Costuas, Karine, Saillard, Jean-Yves
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 26.12.2005
Subjects
Chemical Sciences
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Summary:A topological analysis of the electron density in the ketene complex (η5-MeC5H4)(CO)2Mn[η2-OCC((μ-η2-C⋮CPh)Co2(CO)6)Ph] indicates a predisposition for the carbene component of the ketene ligand to bind the neighboring C atom of the adjacent CO ligand.
Bibliography:ark:/67375/TPS-4R020WCB-4
istex:2476762780A67FDF6791C1FCCB47687AAEF5D3E5
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/ic051239p