Effect of pH, temperature, humic acid and coexisting anions on reduction of Cr(Ⅵ) in the soil leachate by nZVI/Ni bimetal material

• Published in: Environmental pollution (1987) Vol. 227; pp. 444 - 450
• Main Authors: Zhu, Fang, Li, Luwei, Ren, Wentao, Deng, Xiaoqiang, Liu, Tao
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.08.2017
• Subjects: Anions; Chromium - analysis; Chromium - chemistry; Cr(Ⅵ); Environmental Restoration and Remediation - methods; Humic Substances - analysis; Hydrogen-Ion Concentration; Iron - chemistry; Kinetics; Microscopy, Electron, Scanning; nZVI/Ni bimetal materials; Photoelectron Spectroscopy; Soil - chemistry; Soil leachate; Temperature; Thermodynamics; Water Pollutants, Chemical - analysis; Water Pollutants, Chemical - chemistry; X-Ray Diffraction; Soil leachate; Thermodynamics; nZVI/Ni bimetal materials; Kinetics; Cr(Ⅵ)
• ISSN: 0269-7491; 1873-6424
• DOI: 10.1016/j.envpol.2017.04.074

Nano zero valent iron/Ni bimetal materials (nZVI/Ni) were prepared by borohydride reduction method to remediate toxic Cr(Ⅵ) contaminated in soil leachate. nZVI/Ni was characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS). Different factors including pH value of soil leachate, reaction time, temperature, humic acid and coexisting anions (SO42-, NO3−, HCO3−, CO32-) were studied to analyze the reduction rate. Results showed that the reduction rate of Cr(Ⅵ) could reach 99.84% under the condition of pH of 5 and temperature of 303 K. pH values and temperature of soil leachate had a significant effect on the reduction efficiency, while humic acid had inhibition effect for the reduction reaction. SO42-, HCO3− and CO32- had inhibition effect for reduction rate, while NO3− barely influenced the reduction process of nZVI/Ni. Moreover, Langumir-Hinshelwood first order kinetic model was studied and could describe the reduction process well. The thermodynamic studies indicated that the reaction process was endothermic and spontaneous. Activation energy was 143.80 kJ mol−1, showing that the reaction occurred easily. Therefore, the study provides an idea for nZVI/Ni further research and practical application of nZVI/Ni in soil remediation. [Display omitted] •nZVI/Ni was used to remediate Cr(Ⅵ) in the soil leachate and has good reduction rate.•The reduction rate of Cr(Ⅵ) exceeded 99% at pH 5 and temperature 313 K.•SO42-, HCO3− and CO32- could inhibit the reaction rate between nZVI/Ni and Cr(Ⅵ).•The reduction process followed Langumir-Hinshelwood first order kinetic model.