First Enantiospecific Synthesis of (−)-Parvifoline and (−)-Curcuquinone

The first enantiospecific synthesis of (−)-parvifoline, employing ring-closing metathesis as the key step, and (−)-curcuquinone from naturally occurring (R)-(+)-citronellal is described.

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Bibliographic Details
Published inJournal of organic chemistry Vol. 71; no. 23; pp. 8986 - 8988
Main Authors Chavan, Subhash P, Thakkar, Mahesh, Jogdand, Ganesh F, Kalkote, Uttam R
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 10.11.2006
Amer Chemical Soc
Subjects
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Chemistry, Organic
Exact sciences and technology
Molecular Structure
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
Sesquiterpenes - chemical synthesis
Sesquiterpenes - chemistry
Stereoisomerism
Terpenoids
SESQUITERPENES
OXIDATION
ALCOHOLS
ABSOLUTE-CONFIGURATION
PARVIFOLINE
(+/-)-PARVIFOLINE
METATHESIS
Citronellal
Terpenoid
Cyclization
Metathesis
Monoterpene
Enantiospecificity
Chemical synthesis
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Summary:The first enantiospecific synthesis of (−)-parvifoline, employing ring-closing metathesis as the key step, and (−)-curcuquinone from naturally occurring (R)-(+)-citronellal is described.
Bibliography:ark:/67375/TPS-DJVR589W-H
istex:EEDCA910FA9D7446D0F000CAB7850DFBB9A2A9E8
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo061730d