Synthesis of 10-nm Scale Oligothiophene Molecular Wires Bearing Anchor Units at Both Terminal Positions

Oligothiophenes with the length of ca.10 nm bearing anchor units (a protected thiol group or trimethylsilylethynyl) at both terminal positions in the conjugated backbone have been synthesized by the block-coupling synthetic strategy. Their electronic properties were clarified by spectroscopic and el...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 72; no. 7; pp. 2659 - 2661
Main Authors Endou, Masaru, Ie, Yutaka, Kaneda, Takahiro, Aso, Yoshio
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 30.03.2007
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Exact sciences and technology
Organic chemistry
Physical Sciences
Science & Technology
SCHEME
ELECTRON-TRANSFER
THIOESTER TERMINI
ALLIGATOR CLIPS
JUNCTIONS
COMPONENTS
DEVICES
FABRICATION
SEXITHIOPHENES
EFFICIENT
Electronic properties
Thiol
Molecular wires
Electrochemistry
Conjugated compound
Spectrophotometry
Chemical synthesis
Protection
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Summary:Oligothiophenes with the length of ca.10 nm bearing anchor units (a protected thiol group or trimethylsilylethynyl) at both terminal positions in the conjugated backbone have been synthesized by the block-coupling synthetic strategy. Their electronic properties were clarified by spectroscopic and electrochemical measurements.
Bibliography:ark:/67375/TPS-X78MXSGV-H
istex:BF93355E0708509AA88FD0A9A4E07FB9F53267D6
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo062204p