Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates

A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds a...

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Published inOrganic letters Vol. 17; no. 5; pp. 1256 - 1259
Main Authors Sardzinski, Logan W, Wertjes, William C, Schnaith, Abigail M, Kalyani, Dipannita
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 06.03.2015
Amer Chemical Soc
Subjects
Alkanesulfonates - chemistry
Arylsulfonates - chemistry
Biphenyl Compounds - chemical synthesis
Biphenyl Compounds - chemistry
Catalysis
Chemistry
Chemistry, Organic
Fluorobenzenes - chemistry
Halogens - chemistry
Hydrocarbons, Halogenated - chemical synthesis
Hydrocarbons, Halogenated - chemistry
Letter
Molecular Structure
Nickel - chemistry
Physical Sciences
Science & Technology
POTASSIUM POLYFLUOROBENZOATES
ETHERIFICATION
ALLYL ARYL
ALKENYLATION
ARYLATION
CARBOXYLIC-ACIDS
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Summary:A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds are obtained using these newly developed Ni-catalyzed decarboxylative cross-coupling reactions.
Bibliography:NIH RePORTER
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.5b00241