Phototransformation of Propiconazole In Aqueous Media

• Published in: Journal of agricultural and food chemistry Vol. 49; no. 11; pp. 5377 - 5382
• Main Authors: Vialaton, Delphine, Pilichowski, Jean-François, Baglio, Daniela, Paya-Perez, Ana, Larsen, Bo, Richard, Claire
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 01.11.2001
• Subjects: Agronomy. Soil science and plant productions; Applied sciences; Biological and medical sciences; Continental surface waters; Exact sciences and technology; Fundamental and applied biological sciences. Psychology; Fungicides, Industrial - chemistry; Kinetics; Natural water pollution; Photochemistry; Pollution; Soil and water pollution; Soil science; Spectrum Analysis; Sunlight; Triazoles - chemistry; Water - chemistry; Water treatment and pollution; Light effect; Chemical transformation; Propiconazole; Pollutant behavior; Pesticides; HPLC chromatography; Systemic; Conazoles; Fungicide; Hydrolysis; Dechlorination; Humus; Cyclization; Photolysis; Aqueous medium; Triazole derivatives; Oxidation; Water pollution; Measurement method; Solar radiation; Mass spectrometry; Photochemical degradation; Photochemistry
• ISSN: 0021-8561; 1520-5118
• DOI: 10.1021/jf010253r

The photolysis of propiconazole in pure water, in water containing humic substances, and in natural water was investigated. The reaction rates were determined, and the main photoproducts were identified with the help of HPLC−mass spectrometry and by NMR. The quantum yield for direct photolysis was 0.11 ± 0.01 at the maximum of absorption (269 nm). Photocyclization after HCl elimination and photohydrolysis of the cyclized intermediate were the main reaction pathways at 254 nm. By contrast, oxidation prevailed over dechlorination in simulated or natural solar light. Humic substances (10 mg·L-1) and naturally occurring chromophores contained in natural water enhanced the rate of propiconazole photodegradation in solar light. Half-life in June in Clermont-Ferrand (latitude 46°N) was found to be 85 ± 10 h in pure water and 60 ± 10 h in natural water; showing that photodegradation of propiconazole in natural waters involves both direct photolysis and photoinduced reactions. Keywords: Propiconazole; direct photolysis; photoinduced transformation; humic substances; natural water; solar light