Effect of Particle Shape on Capillary Forces Acting on Particles at the Air–Water Interface

• Published in: Langmuir Vol. 29; no. 25; pp. 7903 - 7911
• Main Authors: Chatterjee, Nirmalya, Flury, Markus
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 25.06.2013
• Subjects: Air; Chemistry; contact angle; Exact sciences and technology; General and physical chemistry; polyacrylic acid; roughness; Solid-liquid interface; Surface physical chemistry; Surface Properties; Surface-Active Agents - chemistry; Water - chemistry; Gas liquid interface; Force; Roughness; Contact angle; Air water interface; Printer; Orientation; Displacement; Particle; Surface properties; Calculation; Particle shape; Anchoring
• ISSN: 0743-7463; 1520-5827; 1520-5827
• DOI: 10.1021/la4017504

The capillary forces exerted by moving air–water interfaces can dislodge particles from stationary surfaces. The magnitude of the capillary forces depends on particle shape, orientation, and surface properties, such as contact angle and roughness. The objective was to quantify, both experimentally and theoretically, capillary force variations as an air–water interface moves over the particles. We measured capillary forces as a function of position, i.e., force–position curves, on particles of different shape by using force tensiometry. The particles (5 mm nominal size) were made of polyacrylate and were fabricated using a 3D printer. Experimental measurements were compared with theoretical calculations. We found that force–position curves could be classified into in three categories according to particle shapes: (1) curves for particles with round cross sections, such as spheroidal particles, (2) curves for particles with fixed cross sections, such cylindrical or cubical particles, and (3) curves for particles with tapering cross sections, such as prismatic or tetrahedral particles. Spheroidal particles showed a continuously varying capillary force. Cylindrical or cubical particles showed pronounced pinning of the air–water interface line at edges. The pinning led to an increased capillary force, which was relaxed when the interface snapped off from the edges. Particles with tapering cross section did not show pinning and showed reduced capillary forces as the air–water interface line perimeter and displacement cross section continuously decrease when the air–water interface moved over the particles.