Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes

The addition of heteroatom-hydrogen (Het-H) bonds across the carbon-carbon triple bond, catalyzed by transition-metal complexes, is one of the most interesting and intriguing subjects in organic chemistry. To analyze the state of art of this important field, Alonso et al decided to consider all thes...

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Bibliographic Details
Published inChemical reviews Vol. 104; no. 6; pp. 3079 - 3160
Main Authors Alonso, Francisco, Beletskaya, Irina P, Yus, Miguel
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 01.06.2004
Subjects
Alkynes
Alkynes - chemistry
Catalysis
Chemical bonds
Comparative studies
Hydrogen
Hydrogen - chemistry
Metal complexes
Metals, Heavy - chemistry
Molecular Structure
Organic chemistry
Stereoisomerism
Transition Elements - chemistry
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Summary:The addition of heteroatom-hydrogen (Het-H) bonds across the carbon-carbon triple bond, catalyzed by transition-metal complexes, is one of the most interesting and intriguing subjects in organic chemistry. To analyze the state of art of this important field, Alonso et al decided to consider all these reactions from a mechanistic point of view, using the known data to carry out a comparative study for the different types of reactions.
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ISSN:0009-2665
1520-6890
DOI:10.1021/cr0201068