Melting relations of Ca–Mg carbonates and trace element signature of carbonate melts up to 9 GPa – a proxy for melting of carbonated mantle lithologies

• Published in: European journal of mineralogy (Stuttgart) Vol. 34; no. 5; pp. 411 - 424
• Main Authors: Sieber, Melanie J., Wilke, Max, Appelt, Oona, Oelze, Marcus, Koch-Müller, Monika
• Format: Journal Article
• Language: English
• Published: Göttingen Copernicus GmbH 06.10.2022; Copernicus Publications
• Subjects: Analysis; Calcium; Carbonates; Carbonation; Composition; Crystals; Depletion; Dolomite; Earth mantle; Environmental aspects; Experiments; Fractionation; High pressure; Laboratories; Magnesite; Magnesium carbonate; Melting; Melting points; Melts; Mid-ocean ridges; Periclase; Rare earth elements; Silica; Silicates; Slabs; Temperature; Testing; Thermal properties; Trace elements; Upper mantle
• ISSN: 1617-4011; 0935-1221; 1617-4011
• DOI: 10.5194/ejm-34-411-2022

The most profound consequences of the presence of Ca–Mg carbonates (CaCO3–MgCO3) in the Earth's upper mantle may be to lower the melting temperatures of the mantle and control the melt composition. Low-degree partial melting of a carbonate-bearing mantle produces CO2-rich, silica-poor melts compositionally imposed by the melting relations of carbonates. Thus, understanding the melting relations in the CaCO3–MgCO3 system facilitates the interpretation of natural carbonate-bearing silicate systems. We report the melting relations of the CaCO3–MgCO3 system and the partition coefficient of trace elements between carbonates and carbonate melt from experiments at high pressure (6 and 9 GPa) and temperature (1300–1800 ∘C) using a rocking multi-anvil press. In the absence of water, Ca–Mg carbonates are stable along geothermal gradients typical of subducting slabs. Ca–Mg carbonates (∼ Mg0.1–0.9Ca0.9–0.1CO3) partially melt beneath mid-ocean ridges and in plume settings. Ca–Mg carbonates melt incongruently, forming periclase crystals and carbonate melt between 4 and 9 GPa. Furthermore, we show that the rare earth element (REE) signature of Group-I kimberlites, namely strong REE fractionation and depletion of heavy REE relative to the primitive mantle, is resembled by carbonate melt in equilibrium with Ca-bearing magnesite and periclase at 6 and 9 GPa. This suggests that the dolomite–magnesite join of the CaCO3–MgCO3 system might be useful to approximate the REE signature of carbonate-rich melts parental to kimberlites.