On the Influence of the Menthol Moiety on the Transport Properties of a Homologue Series of Functionalized Bis(trifluoromethylsulfonyl)imide Room-Temperature Ionic Liquids: A Quest for the Structure–Property Relationship

• Published in: The journal of physical chemistry. B Vol. 125; no. 30; pp. 8502 - 8510
• Main Authors: Feder-Kubis, Joanna, Gardas, Ramesh L, Geppert-Rybczyńska, Monika
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 05.08.2021
• Subjects: B: Liquids; Chemical and Dynamical Processes in Solution
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/acs.jpcb.1c03827

This study explores the transport properties of bis­(trifluoromethylsulfonyl)­imide-based ionic liquids with a naturally derived (1R,2S,5R)-(−)-menthol moiety in the cationic part. In particular, we investigated the dependence of the dynamic viscosity and electrical conductivity as functions of the alkyl chain length. An important finding of this study is that both properties show nonmonotonic behavior with respect to the alkyl chain length. The nonmonotonic dependency is an obstacle for establishing the relationships between the structure and transport properties of homologues. To overcome this difficulty, we recommend fast property screening using a theoretical model that we developed, which allows for efficient viscosity prediction by means of the group contribution method. As demonstrated in this study, the model allows for reliable predictions of viscosity in the studied series with an overall relative deviation of less than 8%.