Additive- and Photocatalyst-Free Borylation of Arylazo Sulfones under Visible Light

We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparatio...

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Published inJournal of organic chemistry Vol. 83; no. 20; pp. 12831 - 12837
Main Authors Xu, Yuliang, Yang, Xinying, Fang, Hao
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.10.2018
Amer Chemical Soc
Subjects
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
organic chemistry
organic compounds
Physical Sciences
Science & Technology
METAL-FREE BORYLATION
DECARBOXYLATIVE BORYLATION
SELECTIVE REACTIONS
ROOM-TEMPERATURE
ARYLBORONIC ESTERS
CROSS-COUPLING REACTION
NI-CATALYZED BORYLATION
ALKOXY DIBORON REAGENTS
SYNTHETIC ROUTE
IN-SITU
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Abstract We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.
AbstractList We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.
We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.
Author Fang, Hao
Xu, Yuliang
Yang, Xinying
AuthorAffiliation Department of Medicinal Chemistry, Key Laboratory of Chemical Biology (Ministry of Education), School of Pharmacy
AuthorAffiliation_xml – name: Department of Medicinal Chemistry, Key Laboratory of Chemical Biology (Ministry of Education), School of Pharmacy
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  givenname: Yuliang
  surname: Xu
  fullname: Xu, Yuliang
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  givenname: Xinying
  surname: Yang
  fullname: Yang, Xinying
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  givenname: Hao
  orcidid: 0000-0002-2879-5146
  surname: Fang
  fullname: Fang, Hao
  email: haofangcn@sdu.edu.cn
BackLink https://www.ncbi.nlm.nih.gov/pubmed/30256639$$D View this record in MEDLINE/PubMed
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Keywords METAL-FREE BORYLATION
DECARBOXYLATIVE BORYLATION
SELECTIVE REACTIONS
ROOM-TEMPERATURE
ARYLBORONIC ESTERS
CROSS-COUPLING REACTION
NI-CATALYZED BORYLATION
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Snippet We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows...
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SubjectTerms chemical reactions
chemical structure
Chemistry
Chemistry, Organic
organic chemistry
organic compounds
Physical Sciences
Science & Technology
Title Additive- and Photocatalyst-Free Borylation of Arylazo Sulfones under Visible Light
URI http://dx.doi.org/10.1021/acs.joc.8b01662
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