Additive- and Photocatalyst-Free Borylation of Arylazo Sulfones under Visible Light

We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparatio...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 83; no. 20; pp. 12831 - 12837
Main Authors Xu, Yuliang, Yang, Xinying, Fang, Hao
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.10.2018
Amer Chemical Soc
Subjects
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
organic chemistry
organic compounds
Physical Sciences
Science & Technology
METAL-FREE BORYLATION
DECARBOXYLATIVE BORYLATION
SELECTIVE REACTIONS
ROOM-TEMPERATURE
ARYLBORONIC ESTERS
CROSS-COUPLING REACTION
NI-CATALYZED BORYLATION
ALKOXY DIBORON REAGENTS
SYNTHETIC ROUTE
IN-SITU
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Summary:We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0022-3263
1520-6904
1520-6904
DOI:10.1021/acs.joc.8b01662