Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines

A highly efficient Rh­(III)-catalyzed direct C–H chalcogenation of phenols and anilines has been achieved with the assistance of the 2-pyridyl group. The reaction features a broad substrate scope, good functional group tolerance, complete monothiolation selectivity, and easily removable directing gr...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 82; no. 23; pp. 12430 - 12438
Main Authors Yang, Shiping, Feng, Boya, Yang, Yudong
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 01.12.2017
Amer Chemical Soc
Subjects
chemical reactions
Chemistry
Chemistry, Organic
moieties
organic chemistry
phenols
Physical Sciences
Science & Technology
ANTITUMOR EVALUATION
ROOM-TEMPERATURE
C-H CHALCOGENATION
S-ARYLATION
THIOLATION
WHITE-LIGHT EMISSION
ARYL HALIDES
BOND FORMATION
ACTIVATED DELAYED FLUORESCENCE
DERIVATIVES
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Summary:A highly efficient Rh­(III)-catalyzed direct C–H chalcogenation of phenols and anilines has been achieved with the assistance of the 2-pyridyl group. The reaction features a broad substrate scope, good functional group tolerance, complete monothiolation selectivity, and easily removable directing group.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
1520-6904
DOI:10.1021/acs.joc.7b02221