Sr–Nd–Pb isotope systematics and clinopyroxene-host disequilibrium in ultra-potassic magmas from Toro-Ankole and Virunga, East-African Rift: Implications for magma mixing and source heterogeneity

• Published in: Lithos Vol. 210-211; pp. 260 - 277
• Main Authors: Muravyeva, N.S., Belyatsky, B.V., Senin, V.G., Ivanov, A.V.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2014
• Subjects: Clinopyroxene; East African Rift; Isotope composition; Magma mixing; Mantle source heterogeneity; Africa, East African Rift; Africa; Mantle source heterogeneity; Magma mixing; Isotope composition; East African Rift; Clinopyroxene
• ISSN: 0024-4937; 1872-6143
• DOI: 10.1016/j.lithos.2014.09.011

Nd, Pb and Sr isotope ratios have been determined for kamafugite lava and clinopyroxene phenocrysts from Bunyaruguru (Toro-Ankole) and Virunga volcanic fields of the East African Rift. The whole rock Sr–Nd isotopic signatures of kamafugites (87Sr/86Sr: 0.70463–0.70536; 143Nd/144Nd: 0.51249–0.51255) suggest derivation from an EM1-type mantle source. In contrast, Pb isotopic compositions of the same samples (206Pb/204Pb: 19.00–19.57; 207Pb/204Pb: 15.69–15.74; 208Pb/204Pb: 39.30–40.26) reveal a similarity to EM2-type mantle. New Nd, Pb and Sr isotopic data for clinopyroxene (87Sr/86Sr: 0.70473–0.70503; 143Nd/144Nd: 0.51250–0.51254; 206Pb/204Pb: 18.04–18.17; 207Pb/204Pb: 15.58–15.60; 208Pb/204Pb: 38.09–38.23) suggest derivation from an EM1-like source, and indicate Sr and Pb isotope disequilibrium between clinopyroxene and corresponding host rock. Moreover, clinopyroxenes exhibiting a greater degree of isotopic disequilibrium with their host rock are more sodic in composition. The isotopic disequilibrium is corroborated by the presence of chemical zoning within clinopyroxene, which suggests rapid magma ascent rates preventing melt homogenization. The Pb isotopic ratios for both mineral and corresponding whole rock, together with published data on East African rift-related alkaline centers, define a trend interpreted to represent a mixing line for melts derived from sources such as EM1 and as HIMU. The similar isotopic compositions for clinopyroxene from the different volcanic rocks within the East African Rift suggest the existence of a common, older mantle source for their parental melts. The origin of these melts can be attributed to an enrichment event ~400–500Ma, i.e., significantly prior the younger ultrapotassic magmatism. Our preferred interpretation for the results reported here involves the mixing of melts derived from EM1- and HIMU-like sources, which were rapidly transported to the Earth's surface. The primary magmas formed as the result of melting of a heterogeneous (on kilometer scale) mantle source consisting of peridotite and pyroxenite. •Clinopyroxenes phenocrysts and xenocrysts from volcanic rocks store the characteristics of their mantle source.•Clinopyroxenes in ultra-potassium magmas studied are in Sr–Pb disequilibrium with host rock.•The type of Sr isotope disequilibrium correlates with clinopyroxene major chemistry.•Common source of parental melts was supported by Sr–Pb clinopyroxenes isotopic characteristics.•Pb–Sr–Nd isotope composition of mantle source for East-African Rift volcanic rocks is close to EM1.