The degree of aluminum avoidance in aluminosilicate glasses

• Published in: The American mineralogist Vol. 84; no. 5-6; pp. 937 - 945
• Main Authors: Lee, Sung Keun, Stebbins, Jonathan F
• Format: Journal Article
• Language: English
• Published: Washington Mineralogical Society of America 01.06.1999; Walter de Gruyter GmbH
• Subjects: aluminosilicates; Aluminum; cations; Comparative analysis; electron probe data; experimental studies; formula; glasses; igneous rocks; lattice; metals; Mineralogy; sample preparation; silica; silicates; spectra; statistical analysis; thermodynamic properties; Thermodynamics; volcanic rocks
• ISSN: 0003-004X; 1945-3027
• DOI: 10.2138/am-1999-5-630

For two series of aluminosilicate glasses on the SiO2-NaAlO2 and SiO2-CaAl2O4 joins, 29Si magic-angle-spinning (MAS) NMR spectra were measured. Systematic variations in peak positions and widths with composition are closely related to the extent of ordering of Si and Al cations. A statistical thermodynamic model based on the quasi-chemical approximation was formulated to calculate the proportions of SiO4 groups with varying numbers of Al neighbors and thus to quantify the extent of ordering. Multiple spectra in each compositional series were fitted simultaneously with several peaks representing each of these structural species and with area constraints generated by the model. The extent of aluminum avoidance (Q), which was defined using the relative lattice energy differences among the linkages Si-O-Si, Si-O-Al, and Al-O-Al, was optimized for each series. For the calcium aluminosilicates, the best fit is with 0.8≤Q≤0.875, where Q = 1 represents perfect Al-avoidance. For the sodium series, Q was found to be larger (0.93≤Q≤0.99), as expected from energetic considerations and from known variations in ordering in minerals. The contributions to the overall configurational entropy and heat capacity from Si-Al disorder can be calculated, and are significant fractions of experimentally estimated values. However, major contributions must also come from other sources of disorder, such as "topological" disorder of bond angles and length.