Primary and secondary kinetic deuterium isotope effects and transition-state structures for benzylic chlorination and bromination of toluene

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 109; no. 16; pp. 4926 - 4930
Main Authors Hanzlik, Robert P, Schaefer, Angela R, Moon, Joseph B, Judson, Charles M
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.08.1987
Subjects
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Phase transfer catalysis
Deuterium
Chlorination
Hydrocarbon
Bromination
Cytochrome P450
Toluene
Biomimetic reaction
Hydrogen Isotopes
Kinetic isotope effect
Hydrogen abstraction
Transition state
Halogenation
Benzenic compound
Rate constant
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More Information
Bibliography:istex:3A74D65150BCC9F5E252D9C3379611763047BAAD
ark:/67375/TPS-486XC41K-H
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00250a028