Evidence for adsorption of the cobaltocenium cation and precipitation of uncharged cobaltocene at the platinum microelectrode-acetonitrile interface in the absence of supporting electrolyte

The reduction of the cobaltocenium cation to uncharged cobaltocene and to the cobaltocenium anion was examined voltametrically in acetonitrile in the presence and absence of supporting electrolyte using platinum microdisk electrodes.

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Bibliographic Details
Published inAnalytical chemistry (Washington) Vol. 65; no. 20; pp. 2724 - 2730
Main Authors Cooper, John B, Bond, Alan M
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 15.10.1993
Subjects
Adsorption
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Study of interfaces
Water
Chemical precipitation
Electrode electrolyte interface
Transition metal
Experimental study
Carbon
Chemical reduction
Organic solvent
Adsorption
Platinum
Acetonitrile
Microelectrode
Electrochemical reaction
Platinoid
Disk electrode
Glassy state
Passivation
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Summary:The reduction of the cobaltocenium cation to uncharged cobaltocene and to the cobaltocenium anion was examined voltametrically in acetonitrile in the presence and absence of supporting electrolyte using platinum microdisk electrodes.
Bibliography:ark:/67375/TPS-FW87NT1V-C
istex:9A5F9C2EC65EB0CC1EB04178E5927CDD3F639707
ISSN:0003-2700
1520-6882
DOI:10.1021/ac00068a004