Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads

Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV–vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calcul...

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Published inInorganic chemistry Vol. 56; no. 11; pp. 6039 - 6043
Main Authors Kwak, Sang Woo, Choi, Byung Hoon, Lee, Ji Hye, Hwang, Hyonseok, Lee, Junseong, Kwon, Hyoshik, Chung, Yongseog, Lee, Kang Mun, Park, Myung Hwan
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.06.2017
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Summary:Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV–vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calculation and fluoride titration results further supported these intramolecular energy-transfer features.
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.7b00768