A Pd(0)-Catalyzed Diamination of Terminal Olefins at Allylic and Homoallylic Carbons via Formal C−H Activation under Solvent-Free Conditions

This paper describes a novel diamination process of terminal olefins at allylic and homoallylic carbons via formal C−H activation using di-tert-butyldiaziridinone as nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of terminal olefins can be effectively diaminated in good yields with high s...

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 129; no. 24; pp. 7496 - 7497
Main Authors Du, Haifeng, Yuan, Weicheng, Zhao, Baoguo, Shi, Yian
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 20.06.2007
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
INTRAMOLECULAR DIAMINATION
ALKENES
ELECTROPHILIC DIAMINATION
CIS-AMINOPALLADATION
VICINAL DIAMINATION
1,2-DIAMINATION
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Summary:This paper describes a novel diamination process of terminal olefins at allylic and homoallylic carbons via formal C−H activation using di-tert-butyldiaziridinone as nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of terminal olefins can be effectively diaminated in good yields with high stereoselectivity.
Bibliography:istex:389F09E9586880AFB450DAFD56C51F10E2F9248A
ark:/67375/TPS-LDJ1QMLQ-T
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja072080d