Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands

We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and...

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Published inInorganic chemistry Vol. 58; no. 14; pp. 8927 - 8932
Main Authors Ashida, Yuya, Arashiba, Kazuya, Tanaka, Hiromasa, Egi, Akihito, Nakajima, Kazunari, Yoshizawa, Kazunari, Nishibayashi, Yoshiaki
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 15.07.2019
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Summary:We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis­(diphenylphosphino)­pentane worked effectively toward ammonia formation.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.9b01340