Multifunctional Compound Combining Conductivity and Single-Molecule Magnetism in the Same Temperature Range

We report the first highly conducting single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis­(ethylenedioxo)­tetrathiafulvalene], whose conductivity and single-molecule magnetism coexist in the same temperature range. The compound was synthesized by BEDO electrocrystallization in the presence of...

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Published inInorganic chemistry Vol. 57; no. 5; pp. 2386 - 2389
Main Authors Kushch, Nataliya D, Buravov, Lev I, Kushch, Pavel P, Shilov, Gennadii V, Yamochi, Hideki, Ishikawa, Manabu, Otsuka, Akihiro, Shakin, Alexander A, Maximova, Olga V, Volkova, Olga S, Vasiliev, Alexander N, Yagubskii, Eduard B
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.03.2018
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Summary:We report the first highly conducting single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis­(ethylenedioxo)­tetrathiafulvalene], whose conductivity and single-molecule magnetism coexist in the same temperature range. The compound was synthesized by BEDO electrocrystallization in the presence of (Ph4P)2[ReF6]·2H2O and characterized by crystallography and measurements of the conductivity and alternating-current magnetic susceptibility.
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.7b03152